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Issac Blizzard/Black Light (Jamie Foxx/Dijimin Homonsou) - The one who wanted to recreate the Ice age, Reason to get revenge on Captain Planet for exposing him a fraud.TJ the DJ (Sean Kingston) - a famous DJ, Velma has a crush on, Reason:He has a link between Gaia and Blight.

Issac Blizzard (Jamie Foxx) - owner of Blizzard Indaustries, Reason: he seem's to be covering what's going on in the South Wing.Marcie Francis (Rosario Dawson) - a swimsuit model, who often tries to get Daphne to admit that she has a big butt, Reason: She seems smarter than she looks.Wendell Potter (Peter Dinklage) - a dwarf from Scandinavia who is mining in Korea for Gold, Reason: He has Ma-Ti's vest.Blight and Black Light with the eclipse device. Blight (Tessa Auberjonois) - the secondary antagonist, teams up with Black Light in to recreate an eclipse. Black Light (Djimin Homonsou) - the main antagonist, a mysterious phantom who wants to cause darkness, his goal is to create an eternal eclipse, his appearance is a black Darth Vader like suit, riding a black disk.Gaia (Whoopi Goldberg) - helps the gang use the rings.Captain Planet (David Coburn) - is summoned by both the Planeteers and the gang.Blight along with the rest of the Planeteers Ma-Ti (Scott Menville) - gives Scooby the Ring of Heart when he is taken hostage by Black Light and Dr.Gi (Janice Kawaye) - gives Velma the Ring of Water when she is taken hostage by Black Light and Dr.Linka (Kath Saucie) - gives Shaggy the Ring of Wind when she is taken hostage by Black Light and Dr.Wheeler (Joey Dedio) - gives Daphne the Ring of Fire when he is taken hostage by Black Light and Dr.Kwame (LeVar Burton) - gives Fred the Ring of Earth when he is taken hostage by Black Light and Dr.Velma Dinkley (Kate Micucci) - uses the Ring of Water when Gi is taken alongside the Planeteers by Black Light and Dr.Shaggy Rogers (Matthew Lillard) - uses the Ring of Wind when Linka is taken alongside the Planeteers by Black Light and Dr.Daphne Blake (Grey Griffin) - uses the Ring of Fire when Wheeler is taken alongside the Planeteers by Black Light and Dr.Fred Jones (Frank Walker) - uses the Ring of Earth when Kwame is taken alongside the Planeteers by Black Light and Dr.Scooby-Doo (Frank Welker) - uses the Ring of Heart when Ma-Ti is taken alongside the Planeteers by Black Light and Dr.